[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl)prop-1-en-1-yl-κC 1](η5-pentamethylcyclopentadienyl)titanium(III)
نویسندگان
چکیده
The title compound, [Ti(C(10)H(15))(C(20)H(26)Si)], was obtained from the reaction of [Ti{η(5):η(1)-C(5)Me(4)(CH(2))}(η(5)-C(5)Me(5))] with the alkynylsilane PhC(2)SiMe(2)H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si-H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.
منابع مشابه
Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2 N,C 1}(η5-pentamethylcyclopentadienyl)titanium(IV)
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